| 崔洪珊,何杰,徐从波,赵玲玲,王丽平.Ag2O-NiTi-LDH复合材料的构建及其光催化氧化乙硫醇性能研究[J].安徽建筑大学学报,2024,32(): |
| Ag2O-NiTi-LDH复合材料的构建及其光催化氧化乙硫醇性能研究 |
| Construction of Ag2O-NiTi-LDH Composite and Its Photocatalytic Oxidation of Ethyl Mercaptan |
| 投稿时间：2023-09-28 修订日期：2024-01-07 |
| DOI：10.11921/j.issn.2095-8382.20231007001 |
| 中文关键词: 氧化银，镍钛-层状双金属氢氧化物，复合材料，光催化，乙硫醇 |
| 英文关键词: Ag2O NiTi-layered double hydroxide composite photocatalytic ethyl mercaptan |
| 基金项目:安徽省高校自然科学重点项目(KJ2017A587)；安徽省高校自然科学重点项目(KJ2021A1305) |
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| 中文摘要: |
| 本文将氧化银（Ag2O）负载到镍-钛层状双金属氢氧化物（NiTi-LDH）上以构建Ag2O-NiTi-LDH复合材料。通过XRD、SEM、TEM、XPS、UV-vis、电化学工作站和FT-IR等技术对样品进行表征。采用静态吸附-光催化的方法对乙硫醇进行吸附氧化降解。结果表明：复合材料中Ag2O和NiTi-LDH之间存在相互作用，使得Ag2O-NiTi-LDH复合材料比单一基体材料的带隙能小，光生电子-空穴的分离和迁移效率高；在光催化实验中，单一的基体材料NiTi-LDH对乙硫醇的光催化效果不明显，Ag2O和Ag2O-NiTi-LDH虽然都能将乙硫醇光催化氧化成磺酸盐，但Ag2O-NiTi-LDH复合材料光催化氧化降解效率要高于Ag2O。 |
| 英文摘要: |
| In this paper, Ag2O-NiTi-LDH composites were prepared by loading silver oxide (Ag2O) onto Ni-Ti layered double hydroxide (NiTi-LDH). The samples were characterized by a means of XRD, SEM, TEM, XPS, UV-vis, electrochemical workstation and FT-IR technologies. The adsorption and photocatalytic performance of samples on ethyl mercaptan were evaluated by static adsorption-photocatalytic method. The results show that there is an interaction between Ag2O and NiTi-LDH, which makes the band gap energy of Ag2O-NiTi-LDH composite lower than that of itsprecursors, and the efficiency of separation and migration of photo-generated electron-hole is higher. In the photocatalytic experiment, a single precursor NiTi-LDH has no obvious photocatalytic effect on ethyl mercaptan. Both Ag2O and Ag2O-NiTi LDH can photocatalytic oxidize ethyl mercaptan to sulfonates, however, the photocatalytic degradation efficiency of the composite Ag2O-NiTi-LDH has a much higher than that of Ag2O. |
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