文章摘要
腐蚀环境下活性粉末对混凝土自愈性能影响研究
Study on the Influence of Active Powder on the Self-healing Performance of Concrete in Corrosive Environment
投稿时间:2025-10-15  修订日期:2026-01-14
DOI:
中文关键词: 活性化学粉末  腐蚀环境  抗压与劈裂强度  强度恢复率  愈合机理
英文关键词: active chemical powder  corrosive environment  compressive and splitting strength  strength recovery rate  healing mechanism
基金项目:安徽省自然科学基金项目
作者单位邮编
徐沛保* 安徽建筑大学 230601
骆文杰 安徽建筑大学 
纪晓峰 安徽建筑大学 
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中文摘要:
      活性化学粉末在混凝土裂纹愈合和力学性能提升方面起着重要作用,腐蚀环境对活性化学粉末混凝土的自愈性能具有显著影响。为获得适用于不同腐蚀环境条件的自愈混凝土最佳配方,本文基于活性粉末络合剂(甲基硅酸钠与葡萄糖酸钠按2:1比例)、助剂(硅酸铝与硫酸钠按1:1比例)、甲酸钙和碳酸钠,进行了三种环境下的正交实验。通过对抗压强度、劈裂强度及强度恢复率等参数的测试,评估了混凝土的自愈效果,并分析了活性化学粉末在不同腐蚀条件下的作用规律。实验结果表明,腐蚀性离子的侵蚀会导致裂缝的增大,进而加剧混凝土的开裂,影响混凝土的强度;活性化学粉末能够促进水泥水化反应,改善混凝土内部结晶体的分布,从而提高自愈能力。成分分析与微观结构观察表明,活性粉末与混凝土中的氢氧化钙和游离的钙离子等反应,生成硅酸钙凝胶、钙矾石晶体以及碳酸钙沉淀,这些产物在裂纹处积聚,起到了裂纹修复、强度提升和损伤修复的作用。该研究有助于深入了解活性化学粉末对混凝土自修复性能的影响。
英文摘要:
      Reactive chemical powders play an important role in the healing of concrete cracks and the improvement of mechanical properties. The corrosive environment has a significant impact on the self-healing performance of reactive chemical powder concrete. In order to obtain the optimal formula for self-healing concrete suitable for different corrosive environmental conditions, this paper conducted orthogonal experiments in three different environments based on active powder complexing agents (sodium methylsilicate and sodium gluconate in a ratio of 2:1), additives (aluminum silicate and sodium sulfate in a ratio of 1:1), calcium formate, and sodium carbonate. By testing parameters such as compressive strength, splitting strength, and strength recovery rate, the self-healing effect of concrete was evaluated, and the action of active chemical powder under different corrosion conditions was analyzed. The experimental results indicate that the erosion of corrosive ions can lead to an increase in cracks, which in turn exacerbates the cracking of concrete and affects its strength; Activated chemical powders can promote cement hydration reactions, improve the distribution of crystals inside concrete, and thus enhance self-healing ability. The composition analysis and microstructure observation show that the reactive powder reacts with calcium hydroxide and free calcium ions in the concrete to generate calcium silicate gel, ettringite crystal and calcium carbonate precipitation. These products accumulate at the crack and play a role in crack repair, strength improvement and damage repair. This study contributes to a deeper understanding of the impact of reactive chemical powders on the self-healing performance of concrete.
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